The 42-year-old has modeled a range of luxurious high-end ensembles during a photoshoot for the July issue of W magazine.
The shoot is part of a promotional run that the model is currently in the midst of as she prepares for the launch of a new TV reality series titled The Face.
Glamour: Naomi Campbell has modeled high-end clothing and accessories for W magazine. The above image features a Louis Vuitton acrylic and wool jacquard coat and a wool and calfskin bag, also by the French label
The supermodel, who lives in Moscow with her Russian billionaire boyfriend Vladislav Doronin, will mentor aspiring models on the show, which is being made by Oxygen network.
As styled by Giovanna Battaglia, she has been photographed for W in designs by Louis Vuitton, Miu Miu, Prada, Marc Jacobs, Dolce & Gabbana, Etro and Mary Katrantzou.
Photographed by Australian-born snapper Emma Summerton, she also shows off a range of accessories such as a Fendi iPad case, a Missoni clutch, a Bally handbag and Yves Saint Laurent heels.
Miss Campbell, who is rumoured to be looking to buy a villa in Ibiza with Mr Doronin, offered the magazine some advice for younger, less experienced models.
Bold: She wears a striking Prada tricotine argyle dress in the above shot which has been paired with a Prada poplin collar shirt. The look is teamed with a jeweled Prada bag and Malia Mills black velvet underwear
High fashion: She wears a Marc Jacobs wool jacket, Malia Mills velvet underwear, Eclat Jewels diamond brooch, John Hardy two-finger ring, Tod's clutch and Tom Ford sandals
She said: 'Whatever you do, do it 110per cent. That's what my mother taught me, and it's what I've always believed in.'
It seems that the model had prepared plenty of advice in preparation for her small screen role.
Two other high-profile personalities will join Miss Campbell on the show but they are yet to be announced.
Each of the contestants on the show will be competing to become the face of a major brand.
Onwards and upwards: The model will soon play a mentor on the forthcoming reality show The Face. She models a Miu Miu mohair jacket and pants (above) plus a Bally bag and Yves Saint Laurent pumps
Comfortable: The camera loves the model, who sports an Etro embroidered wool coat and Fendi iPad case
Miss Campbell herself has fronted campaigns for Valentino and Ralph Lauren, as well as Hilton hotels and Dunkin' Donuts over the years.
Cover star: Fellow model Karlie Kloss (pictured) is one of the two July cover stars. Joan Smalls features on another version of the magazine
She is certainly well-equipped to give advice to the hopefuls - though her famously fiery temper promises entertaining on-screen moments.
In a press release announcing the news, she said: 'With The Face the audience will get a real insider’s look at this exciting industry that has been so good to me.
She told W magazine that she is a big fan of reality TV.
'I love the Real Housewives - all of them,' she said. 'Of course, I would never expose myself in that way. But I'm happy to share my experiences.'
Although she is renowned for her career in fashion, the supermodel is no stranger to the world of TV.
In 1988, she had a guest role on The Cosby Show.
Miss Campbell has been dating Mr Doronin since 2008.
She originally lived in the UK before relocating to Moscow to be with him.
The couple have a property portfolio that includes houses in Moscow, a private island in Turkey, a luxury retreat in Jamaica and a mansion in Miami.